VIJ Digital library
Articles

Reduction of Heavy Metal (Pb) ions in industrial waste using activated carbon based on used catalysts

Netty Herawati
Chemical Engineering Study Program, University of Muhammadiyah Palembang
Rifdah, Ummi Kalsum
Chemical Engineering Study Program, University of Muhammadiyah Palembang
Nyayu Miftakhul Muthiah
Chemical Engineering Study Program, University of Muhammadiyah Palembang

Submission to VIJ 2023-10-18

Keywords

  • Activated carbon, cracking catalyst, Adsorbent, Tofu Liquid Waste, Pb metal.

Abstract

Used catalyst-based activated carbon is activated carbon made from used catalysts from the crude oil cracking process. The used catalyst used is a type of crystalline Zeolite with a regular structure, which contains elements of Silica Oxide, Alumina Oxide, and Calcium Oxide. The use of organic activated carbon to treat waste has been widely used, the use of used catalyst waste as activated carbon is very potential because the catalyst used for oil company cracking is no longer used. Tofu industry is one of Indonesia's industries dominated by small-scale businesses with limited capital, so most tofu industries do not have waste treatment units, where liquid waste is directly discharged into sewers or water bodies without treatment first. Tofu industrial waste contains pollutants both organic and inorganic. Initial analysis of tofu industry liquid waste containing Pb metal. This study aims to determine the effect of mass variation and stirring time of used catalyst-based activated carbon adsorbent on reducing Heavy Metal Ions (Pb) in tofu industry liquid waste. The adsorption process is carried out with mass variations of activated carbon of 5, 10, 15, 20, and 25 grams. Stirring time variations are 30, 60, 90, 120, and 150 minutes. From the results of the study, it is known that the best condition for reducing Pb content was obtained at a stirring time of 60 minutes and a large catalyst-based activated carbon mass of 66.33%

References

  1. S. Subekti, "PROCESSING TOFU LIQUID WASTE INTO BIOGAS AS AN ALTERNATIVE FUEL," 2011. [Online]. Available:
  2. https://www.publikasiilmiah.unwahas.ac.id/index.php/PROSIDING_SNST_FT/article/view/241
  3. S. Liang et al., "CONCENTRATIONS OF HEAVY METALS IN UNTREATED PRODUCED WATER FROM A CRUDE OIL PRODUCTION PLATFORM IN NIGER-DELTA, NIGERIA ERAKHRUMEN," Proc. Natl. Acad. Sci., Vol. 3, No. 1, pp. 1–15, 2015, [Online]. Available: http://dx.doi.org/10.1016/j.bpj.2015.06.056%0Ahttps://academic.oup.com/bioinformatics/article-abstract/34/13/2201/4852827%0Ainternal-pdf://semisupervised-3254828305/semisupervised.ppt%0Ahttp://dx.doi.org/10.1016/j.str.2013.02.005%0Ahttp://dx.doi.org/10.10
  4. W. W. Nandari, A. Utami, E. Yogafanny, and M. T. Kristiati, "Produced Water Treatment with Bioreactor Membrane in Wonocolo Mining Area," Exergy, Vol. 15, No. 2, p. 34, 2018, DOI: 10.31315/E.V15i2.2384.
  5. X. Wang, J.:Guo, "Adsorption isotherm: Classification, physical meaning, application and solving method.," Chemosphere, Vol. 258, p. 127279, 2020.
  6. M. Gao, X.; Fup, C.; Hao, J.; Zhao, Z.; Long, H.; Li, "Adsorption of heavy metal ions by sodium alginate-based adsorpbent- A review and new perspectives," Int. J. Biol. Macromol, Vol. 164, pp. 4423–4434, 2020.
  7. G. Ray, S.; Das Chapter 12- Adsorption. In process Equipment and Plant design. 2020.
  8. X. L. and P. L. G. Lu, "Reactivation of spent FCC catalyst by mixed acid leaching for efficient catalytic cracking," J. Ind. Eng. Chem, Vol. 92, pp. 236–242.
  9. A. G. A. Amari, H. Gannouni, M. I. Khan, M. K. Almesfer, A. M. Elkhaleefa, "Effect of structure and chemical activation on the adsorption properties of green clay minerals for the removal of cationic dye," Appl. Sci., no. 8 (11), p. DOI: 10. 3390/app8112302., 2018.
  10. M. K. Uddin, "review on the adsorption of heavy metals by clay minerals, with special focus on the past decade," Chem. Eng. J., No. 308, pp. 438– 462. doi: 10.1016/j.cej.2016.09.029, 2017.